It wouldn’t be.
I don’t think it would break all toml
users, but it is a reason to not go with that name in the stdlib.
Not necessarily.
At this point I think a PEP is necessary. I can sponsor it but I don’t have the bandwidth to be an author on it. I would review here and the issue on bugs.python.org potential concerns to address in the PEP. And to be clear, this would be a standards-track PEP and not a packaging PEP, so that means it will be going to python-dev and the SC.