No I don’t think so VS code is not that smart, its pretty smart, but its is extremely flexible and hence you can set the interpreter here. BTW I use both Pycharm and VS code for different things. VS code is very good at getting the file you want type CTL-p and start typing file name and it presents a selection (but Pycharm you need to go via menu for (Navigate) Search Everywhere). VS code is good for git and shows you the history changes in Timeline.
Pycharm is very good for testing and editing python code, also very good at linting.