Please don’t post screenshots of text such as error messages.
The most likely issue is that you have two versions of Python installed, one has Pillow installed and the other doesn’t.
Please run this code and tell us what it does. Copy and paste the output and format it as code:
python -c "import sys; print(sys.version, sys.executable); import PIL"
Please run that from both PyCharm and the Windows command prompt, and compare the results.
This post may also help: